(2,2′-Bipyridine-κ2 N,N′)[N-(2-oxido-1-naphthylidene)threoninato-κ3 O 1,N,O 2]copper(II)
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چکیده
In the title complex, [Cu(C(15)H(13)NO(4))(C(10)H(8)N(2))], the Schiff base ligand is derived from the condensation of 2-hydr-oxy-1-naphthaldehyde and l-threonine. The Cu(II) atom is five-coordinated by one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 2,2'-bipyridine ligand in a distorted square-pyramidal geometry. In the crystal structure, the combination of inter-molecular O-H⋯O and C-H⋯O hydrogen bonds leads to a two-dimensional network.
منابع مشابه
Bis(μ-2-phenylquinoline-4-carboxylato)-κ3 O,O′:O;κ3 O:O,O′-bis[(2,2′-bipyridine-κ2 N,N′)(2-phenylquinoline-4-carboxylato-κ2 O,O′)cadmium(II)]
The neutral binuclear title complex, [Cd(2)(C(16)H(10)NO(2))(4)(C(10)H(8)N(2))(2)], is centrosymmetric, with the inversion center generating the central (μ-O)(2)Cd(2) bridge. The Cd(II) ion is in a strongly distorted CdN(2)O(5) penta-gonal-bipyramidal geometry, defined by two N atoms from one 2,2'-bipyridine ligand and five O atoms from three 2-phenyl-quinoline-4-carboxyl-ate ligands, one monod...
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